Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575342 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
Abstract
Reaction of the cluster Os3(CO)10(μ-H)(μ-γ-C5H3O2) (1), with DMAD under UV irradiation afforded three isomers of the monosubstituted product, Os3(CO)9(μ-γ-C5H3O2)(μ3-MeO2CCHCCO2Me) (2), and a disubstituted product, Os3(CO)8(μ-γ-C5H3O2)(μ3-MeO2CCHCCO2Me)(μ-MeO2CCCCO2Me) (3). The formation of 3 suggests that flipping of the O-heterocycle can occur.
Related Topics
Physical Sciences and Engineering
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Authors
Qi Lin, Weng Kee Leong,