| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575346 | Journal of Organometallic Chemistry | 2005 | 10 Pages |
Abstract
Primary and secondary amines, pyridine and benzophenone imine, can be coordinated in the dinuclear complexes [Fe2{μ-CN(Me)R}(μ-CO)(CO)2(Cp)2][SO3CF3] (R = Me, Xyl) via CO displacement, promoted by Me3NO. The imino complex 13b reacts with p-tolylacetylide, generating C-C and C-N bonds with formation of a new bridging vinylidene-diaminocarbene complexes 15.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Diiron-aminocarbyne complexes with amine or imine ligands: C-N coupling between imine and aminocarbyne ligands promoted by tolylacetylide addition to [Fe2{μ-CN(Me)R}(μ-CO)(CO)(NHCPh2)(Cp)2][SO3CF3]](/preview/png/10575346.png "First Page Preview: Diiron-aminocarbyne complexes with amine or imine ligands: C-N coupling between imine and aminocarbyne ligands promoted by tolylacetylide addition to [Fe2{μ-CN(Me)R}(μ-CO)(CO)(NHCPh2)(Cp)2][SO3CF3]")
Authors
Luigi Busetto, Fabio Marchetti, Stefano Zacchini, Valerio Zanotti, Eleonora Zoli,