Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575355 | Journal of Organometallic Chemistry | 2005 | 5 Pages |
Abstract
Ferrocenylenones are synthesized efficiently by using a Friedel-Crafts acylation reaction. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and β-methylcrotonoyl chlorides react with ferrocene in the presence of a Lewis acid (EtAlCl2 or EtAlCl2-Me3Al) to give the corresponding ferrocenylenones (acryloyl, methacryloyl, crotonoyl, cinnamoyl, and methylcrotonoylferrocenes) in good isolated yields. Besides ferrocenylenones, chloroactylferrocene is also synthesized by this method.
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Physical Sciences and Engineering
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Authors
Ãzdemir Dogan, Volkan Åenol, Serhat Zeytinci, Hasan Koyuncu, Adnan Bulut,