| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575361 | Journal of Organometallic Chemistry | 2005 | 8 Pages |
Abstract
The reaction of BEt3 with the (2-dimethylaminophenyl)alcohols 1-HOX-2-NMe2C6H4 [XÂ =Â CPh2 (1), CCy2 (2), CPh2CH2 (3)] [1:1 (for 1-3) or 1:2 (for 3)] in the presence of tBuCO2H as catalyst gave the BEt2 or BEt derivatives 1-Et2BOX-2-NMe2C6H4 [XÂ =Â CPh2 (4), CCy2 (5), CPh2CH2 (7)] and BEt(1-OCPh2CH2-2-NMe2C6H4)2 (8). Treatment of 5 with acetic acid gave 1-(CH3COO)EtBOCCy2-2-NMe2C6H4 (6). Compounds 4-8 were characterized spectroscopically (NMR, IR, MS), 4, 6, and 8 also by X-ray crystallography.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Harbi T. Al-Masri, Joachim Sieler, Peter C. Junk, Konstantin V. Domasevitch, Evamarie Hey-Hawkins,