Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575364 | Journal of Organometallic Chemistry | 2005 | 11 Pages |
Abstract
Complexes I-III are prepared by reactions of bromodiazocyclopentadienes C5H4 â nBrnN2 (n = 2, 3, 4) with BrM(CO)5 in CF3C6H5 at elevated temperatures. When the reaction of C5Br4N2 and BrRe(CO)5 is conducted at a lower temperature, the η1-pentabromocyclopentadienyl complex (η1-C5Br5)Re(CO)5 (IV) is isolated. All attempts to induce decarbonylation to the III are unsuccessful. The isomeric tribromo complex V is accessed via a debromination sequence.
Related Topics
Physical Sciences and Engineering
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Inorganic Chemistry
Authors
Long V. Dinh, Frank Hampel, J.A. Gladysz,