Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575586 | Journal of Organometallic Chemistry | 2005 | 5 Pages |
Abstract
Hydroindation of arylalkynylphosphonates gives a intermediate which can be hydrolyzed to (E)-2-arylvinylphosphonates in InCl3-NaBH4-MeCN system, a new and simple approach to (E)-2-arylvinylphosphonates from (E)-2-arylalkynylphosphonates has been developed, in which the InCl3-NaBH4-MeCN system was firstly employed in reduction of alkynylphosphonates successfully. A radical mechanism is proposed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Chunyan Wang, Yuanjiang Pan, Deyu Yang,