| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575589 | Journal of Organometallic Chemistry | 2005 | 13 Pages |
Abstract
The synthesis of classical and non-classical ruthenium (II) mixed-ligand hydride complexes RuHTpL(PPh3) and [Ru(η2- H2)TpL(PPh3)]+ with phosphite and tris(pyrazolyl)borate is described. Vinylidene [RuTp{CC(H)R}L(PPh3)]BPh4 and allenylidene [RuTp(CCCR1R2)L(PPh3)]BPh4 complexes were also prepared by allowing η2-H2 derivatives to react with the appropriate HCCR and HCCC(OH)R1R2 alkynes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Gabriele Albertin, Stefano Antoniutti, Marco Bortoluzzi, Gianluigi Zanardo,