| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575606 | Journal of Organometallic Chemistry | 2005 | 5 Pages |
Abstract
The rhodium-catalyzed hydroformylation of 3-acetyl-1-allylpyrrole (1) gives an equimolar mixture of the tetrahydroindolizines 2 and 3 via two different domino processes. Interestingly, 3 forms via a stabilized 8-hydroxyindolizine which, although often postulated as an intermediate in the cyclization mechanism under oxo conditions, has been isolated and characterized here for the first time.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Silvia Rocchiccioli, Roberta Settambolo, Raffaello Lazzaroni,