| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575623 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
Abstract
New four-coordinate nickel(II) complexes of (Ph3P)Ni(o-Tolyl)(ISQ) species with 4,6-di-tert-butyl-N-aryl-o-iminobenzosemiquinonate anion-radical ligands (ISQ) have been prepared and characterized. Complexes contain Ï-bound o-tolyl and neutral donor ligand PPh3. The sterical hindrances of N-aryl in o-iminobenzosemiquinonate ligands lead to the tetrahedral distortion of square-planar configurations of complexes. Complexes are able to exchange of PPh3 on some neutral donor ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Andrey I. Poddel'sky, Vladimir K. Cherkasov, Michail P. Bubnov, Ludmila G. Abakumova, Gleb A. Abakumov,