| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10576291 | Journal of Solid State Chemistry | 2005 | 8 Pages |
Abstract
The spinel structure provides octahedral and tetrahedral coordination for cations. In (MnxFe1-x)3O4, strongly negative enthalpies of mixing, measured by oxide melt solution calorimetry, quantify the dominant role of oxidation-reduction reactions (Mn3++Fe2+=Mn2++Fe3+) in the energetics.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sophie Guillemet-Fritsch, Alexandra Navrotsky, Philippe Tailhades, Hervé Coradin, Miaojun Wang,