Article ID Journal Published Year Pages File Type
10576310 Journal of Solid State Chemistry 2005 11 Pages PDF
Abstract
With increasing doping, the enthalpy of formation of the fully oxidized sample in both Ca and Sr-doped systems becomes more endothermic. This destabilization effect is attributed to the large endothermic enthalpy of oxygen vacancy formation that over-rides the exothermic enthalpies of oxidation.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
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