Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10576325 | Journal of Solid State Chemistry | 2005 | 7 Pages |
Abstract
Both the homometal cluster [P(ph4)]2[Mo2O2(μ-S)2(S2)2] (1) and [Mo2O2(μ-S)2(Et2dtc)2] (2) (Et2dtc=diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145Ã10â30 esu for (1) and 5.428Ã10â30 esu for (2).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yong Li, Jing Lu, Xiao-Bing Cui, Ji-Qing Xu, Ke-Chang Li, Hua-Ying Sun, Guang-Hua Li, Ling-yun Pan, Qing-Xin Yang,