| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10579703 | Tetrahedron: Asymmetry | 2005 | 10 Pages |
Abstract
Treatment of mixed acetal glycosides as well as other types of carbohydrate mixed acetals with TMS-triflate and an amine base provides vinyl glycosides or carbohydrate vinyl ethers. Hetero-Diels-Alder reactions of carbohydrate 3-O- and 6-O-vinyl ethers with ethyl (E)-ethoxymethylenepyruvate were carried out as part of a model study for the synthesis of deoxygenated disaccharides of antibiotics.
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Authors
Kevin D. Hughes, Tuan-Linh N. Nguyen, Damian Dyckman, Doreen Dulay, Walter J. Boyko, Robert M. Giuliano,