Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10579891 | Tetrahedron: Asymmetry | 2007 | 8 Pages |
Abstract
The effectiveness of several spiroborate ester catalysts was investigated in the asymmetric borane reduction of 2-, 3-, and 4-acetylpyridines under different reaction conditions. Highly enantiomerically enriched 1-(2-, 3-, and 4-pyridyl)ethanols and 1-(heterocyclic)ethanols were obtained using 1-10% catalytic loads of the spiroborate 5 derived from diphenylprolinol and ethylene glycol.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Viatcheslav Stepanenko, Melvin De Jesús, Wildeliz Correa, Irisbel Guzmán, Cindybeth Vázquez, Lymaris Ortiz, Margarita Ortiz-Marciales,