Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10605626 | Carbohydrate Research | 2011 | 5 Pages |
Abstract
After stereoselective addition of N-iodosuccinimide to glycals subsequent dehalogenation results in formation of N-glycopyranosyl succinimides. By UV irradiation both azepindiones and preferentially [5.3.1.02,6] tricyclic oxalactams could be obtained. Their transformation into a number of novel sugar conjugates resembling some prominent alkaloid N-pyrrol components by thiation and reduction is reported.
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Authors
Carsten-Endres Sowa, Joachim Thiem,