Article ID Journal Published Year Pages File Type
10605626 Carbohydrate Research 2011 5 Pages PDF
Abstract
After stereoselective addition of N-iodosuccinimide to glycals subsequent dehalogenation results in formation of N-glycopyranosyl succinimides. By UV irradiation both azepindiones and preferentially [5.3.1.02,6] tricyclic oxalactams could be obtained. Their transformation into a number of novel sugar conjugates resembling some prominent alkaloid N-pyrrol components by thiation and reduction is reported.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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