| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10606111 | Carbohydrate Research | 2006 | 10 Pages |
Abstract
Perbenzylated methyl pentofuranosides were submitted to the action of three alkylalanes and regioselective debenzylation at O-2 of the four pentoses was observed when choosing the right match between anomeric configuration and aluminium reagent. Diisobutylalane (DIBAL-H) allowed an easy access to reduced open-chain compounds, whereas trimethylalane (TMAL) stereoselectively produced methylated open chain derivatives.
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Physical Sciences and Engineering
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Organic Chemistry
Authors
Cai Jia, Yongmin Zhang, Li-He Zhang, Pierre Sinaÿ, Matthieu Sollogoub,