| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10606569 | Carbohydrate Research | 2011 | 11 Pages |
Abstract
A facile synthetic route to d-ribo-C20-phytosphingosine 31 and its C2 epimer 32 is described. The Overman rearrangement of allylic trichloroacetimidates derived from the known ribose derivative 7 has been used as the key step. The subsequent functional group interconversions in rearranged products 14 and 15 followed by Wittig olefination, Pd/C-mediated reduction and the removal of protecting groups successfully constructed the final molecules.
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Authors
Miroslava Martinková, Jozef Gonda, Kvetoslava Pomikalová, Jozef KožÃÅ¡ek, Juraj Kuchár,