Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10608516 | European Polymer Journal | 2013 | 11 Pages |
Abstract
⺠Bulk lipase-catalyzed polymerizations, non-fractionated products. ⺠Comonomer feed ratio (oleic diacid:glycerol:linoleic acid) 1:1:0.67, Mn reached 9500 in 8 h. ⺠Glycerol units along chain reached nearly quantitative conversion to trisubstituted units. ⺠Branched chains that mimic triglyceride repeat units. ⺠Calculations performed to determine relative proportion of different substitution patterns of glycerol units.
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Authors
Yu-Rong Zhang, Stephen Spinella, Wenchun Xie, Jiali Cai, Yixin Yang, Yu-Zhong Wang, Richard A. Gross,