Article ID Journal Published Year Pages File Type
10609529 European Polymer Journal 2013 8 Pages PDF
Abstract
► Uncrosslinked PEOEMA exhibit two secondary relaxation processes in the glassy state. ► The β relaxation is suppressed by crosslinking the PEOEMA, remaining the γ relaxation. ► The γ relaxation is due to conformational transitions about the OCH2CH2O bonds. ► The β relaxation may arise from local motions of the polymer backbone. ► The mesoscopic structure appears in the dielectric spectra but not in the mechanical.
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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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