Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10611054 | Carbon | 2005 | 5 Pages |
Abstract
For the first time, graphite fibers have been electrochemically intercalated with Brâ that have the same structure and properties as those intercalated from vapor phase Br2. This was accomplished by intercalating pitch-based Thornel® K-1100 graphite fibers at low temperature (near 0 °C) and high currents (2 A) for long times (6 h). The mechanism appears to be that Brâ is oxidized to aqueous Br2 which, when sufficient local concentration builds up, intercalates the fiber. This was confirmed by intercalating K-1100 fiber in a saturated aqueous Br2 solution without passing an electrical current. The applied voltage does apparently lower the activation energy of the reaction as evidenced by the observation that P-120 and P-100 fibers will not intercalate in aqueous Br2 unless a voltage is applied.
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Authors
James R. Gaier, Nora F. Ditmars, Andrea R. Dillon,