Article ID Journal Published Year Pages File Type
10611296 Carbon 2005 4 Pages PDF
Abstract
Gd@C82 and Gd2@C80 were selectively reduced and extracted from the raw soot in a high yield by using Al-Ni alloy in toluene/tetrahydrofuran (THF). By tuning the ratio of toluene and THF, Gd2@C80 with purity higher than 95% was isolated directly from the raw soot without high performance liquid chromatography (HPLC) purification. Furthermore, we found that the anions of Gd@C82 and Gd2@C80 could react with aqueous NaOH to form water-soluble Gd-metallofullerols, which are potential magnetic resonance imaging contrast agents.
Related Topics
Physical Sciences and Engineering Energy Energy (General)
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