Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10621195 | Acta Materialia | 2005 | 12 Pages |
Abstract
We used a resonant-ultrasound-spectroscopy technique to measure the three independent elastic constants of PdHx, PdDx, and PdTx single crystals at 300 K. For 0.1 < x < 0.62 our PdHx crystals are two-phase mixtures of coherent α and β hydride phases. For increasing x in this range, C44 decreases monotonically whereas Câ²=12(C11-C12) has a concave parabolic dependence. This difference is because Câ² is softened by an anelastic relaxation resulting from acoustic-stress-induced changes in the shape of the coherent lenticular-shape precipitates (β-hydride precipitates in α-hydride matrix and α-hydride precipitates in β-hydride matrix). In the β-phase Câ² and C44 decrease with increasing hydrogen (or deuterium or tritium) content. Furthermore, Câ² exhibits a strong isotope effect whereas C44 does not. This effect is attributed to differences in the excitation of optical phonons in Pd-H, Pd-D and Pd-T.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
R.B. Schwarz, H.T. Bach, U. Harms, D. Tuggle,