Article ID Journal Published Year Pages File Type
10625716 Ceramics International 2014 10 Pages PDF
Abstract
A novel and facile synthetic approach has been trialed, and attempted with success in the preparation of two phosphors namely, a red emitting CaSrSiO4:Eu3+ and a green emitting CaSrSiO4:Eu2+. These phosphors were successfully synthesized using a simple co-precipitating solvo-thermal strategy wherein tetraethyl orthosilicate (TEOS) as silica source and the acetate precursors of strontium (Sr2+), calcium (Ca2+) and europium (Eu3+) are utilized. The material so obtained is subjected to an extensive photoluminescence behavior study. The concentration of the dopant (Eu3+and Eu2+) plays a significant role in the determination of photoluminescence behavior and hence a systematic and in-depth experimental studies were done and the results are synchronized. On interpretation of the output, it came to light that an intense emission signals sparked in the red region (590 and 615 nm) in the case of phosphor doped with Eu3+, which is excited under near ultra violet (395 nm) and blue (466 nm) region. In case of the CaSrSiO4 sample doped with Eu2+, an intense broad green signal (~510 nm) is obtained under the excitation range of 350-430 nm. The results obtained are quite encouraging and made a strong confirmation as, the solvo-thermally synthesized CaSrSiO4, which is activated by the dopants namely Eu3+ and Eu2+ possesses an immense potential and it is exactly tapped by the adopted methodology. Despite its strong impact, it will also assure a strong revolution in the fabrication and thus the commercialization of white LEDs as both the red and green emitting phosphor.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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