Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10625911 | Ceramics International | 2013 | 7 Pages |
Abstract
High-field ZnO/Bi2O3 varistors co-doped with Mn and Co were synthesized using a two-step co-precipitating process. A Zn2+ solution containing the Mn and Co doping elements was first precipitated into hydroxides, further converted into oxalates and finally calcined to create the doped ZnO phase. Bi3+ precipitated at the grain boundaries thanks to an HNO3 treatment of the ZnO grains. The influence of the precursor type (nitrates or chlorides) and the calcination temperature on the properties of the powders and ceramics were investigated. ICP-AES, microstructural analysis and non-linear voltage measurements were used to characterize the samples. The type of precursor solution was found to have a strong influence on the electrical properties. Furthermore, the calcination temperature modified the microstructure of the powder and consequently also that of the varistor.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Geoffroy Gadacz, Sophie Beaudet-Savignat, Laurence Longuet, Jean-Louis Longuet,