Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10626005 | Ceramics International | 2013 | 7 Pages |
Abstract
A complex impedance of oxyapatites Ca2âxBaxLa4Bi4(SiO4)6O2 (0â¤xâ¤2) prepared by solid state reaction has been investigated. The formation of apatites has been checked by X-ray diffraction, FTIR, Raman and 29Si MAS-NMR techniques. The electric impedance data indicate that relaxation phenomena are strongly dependent on temperature in the 923-1048 K range. The bulk resistance decreases with increasing temperature, showing a typical negative temperature coefficient of resistance (NTCR). ac-Conductivity measurements have been performed on a wide range of frequencies and temperatures. The complex modulus plots have confirmed the presence of bulk contributions. The complex impedance analysis suggests the presence of non-Debye relaxations that would be associated with correlation on ions motion.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
M. Abbassi, R. Ternane, I. Sobrados, A. Madani, M. Trabelsi-Ayadi, J. Sanz,