Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10629209 | Journal of the European Ceramic Society | 2016 | 10 Pages |
Abstract
Oxidation of silicon melt infiltrated SiC/SiC ceramic matrix composites (CMC) was studied in air at 1200-1400 °C for 1, 5, 24 and 48 h. Weight gain and oxide layer thickness measurements revealed the oxidation follows parabolic reaction kinetics with increase in temperature and time. XRD showed the extent of oxide layer (SiO2) formation was greatest after 48 h at 1400 °C: an observation confirmed by X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM) analyses. Oxide layer thickness varied from 1 μm after 48 h at 1200 °C to 8 μm after 48 h at 1400 °C. Oxidation of SiC/SiC composites is both temperature and time dependent with an activation energy of 619 kJ molâ1. BN coatings around SiC fibres showed good resistance to oxidation even after 48 h at 1400 °C.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Nasrin Al Nasiri, Niranjan Patra, Na Ni, Daniel D. Jayaseelan, William E. Lee,