Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10629433 | Journal of the European Ceramic Society | 2016 | 6 Pages |
Abstract
Thorium dioxide is a refractory ceramic material and is difficult to sinter to high density. Commercial powder starts to sinter in SPS under 70 MPa above 1000 °C and compaction is not finished at 1600 °C. In contrast, a 13 nm nanopowder synthesised via low temperature decomposition of thorium oxalate starts to sinter at â¼500 °C; the onset of sintering shifts to higher temperatures for powders with larger crystallites. The initial crystallite size solely affects the onset of sintering, whereas the final stage of sintering is independent of the initial crystallite size for the powders used in this study. Pellets with density well above 95% of the theoretical density were prepared using SPS at sintering temperature of 1600 °C, 70 MPa pressure and 10 min dwell time.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
V. Tyrpekl, M. Cologna, D. Robba, J. Somers,