Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10630260 | Journal of the European Ceramic Society | 2005 | 14 Pages |
Abstract
The creep of the eutectic in its growth direction exhibits an initial transient that is attributed to stress relaxation in the c-ZrO2(Y2O3) phase, but otherwise in steady state shows many of the same characteristics of creep in sapphire single crystals with c-axis orientation. The creep strain rate of the eutectic has stress exponents in the range of 4.5-5.0 and a temperature dependence suggesting a rate mechanism governed by oxygen ion diffusion in the Al2O3. While required TEM evidence is still incomplete, finite element analysis of stress distribution in the two phases and a detailed dislocation model of the creep rate indicate that much of the nano-scale encapsulated c-ZrO2(Y2O3) is too small to deform by creep so that the major contribution to the recorded creep strain is derived from the diffusion-controlled climb of pyramidal edge dislocations in the Al2O3 phase. The evidence suggests that the climbing dislocations in Al2O3 must repeatly circumvent the c-ZrO2(Y2O3) domains acting as dispersoids resulting in the stress exponents larger than 3. The creep model is in very good agreement with the experiments.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
J. Yi, A.S. Argon, A. Sayir,