| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10643140 | Solar Energy | 2005 | 8 Pages |
Abstract
The photooxidation of aniline to azobenzene in ethanol on CdS with natural sunlight and UV irradiation (365Â nm) was studied as a function of [aniline], catalyst loading, airflow rate, solvent composition, etc. The metal sulfide shows sustainable catalytic activity. The product formation is larger with illumination at 254Â nm than at 365Â nm. Electron donors like triphenylphosphine, diphenylamine and hydroquinone favor the photocatalysis. Singlet oxygen quencher, azide ion does not inhibit the oxidation. The photocatalysis occurs in protic and aprotic solvents. The mechanism of photocatalyzed oxidation is discussed and the product formation examined using a kinetic equation.
Related Topics
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Energy
Renewable Energy, Sustainability and the Environment
Authors
C. Karunakaran, S. Senthilvelan,