Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10644377 | Calphad | 2005 | 6 Pages |
Abstract
The Gibbs energy of the liquid phases in the SmCl3-MCl (M=Na, K, Rb, Cs) systems is described by a modified quasi-chemical model. Based on measured phase equilibrium data and experimental thermochemical properties of these binary systems, a set of thermodynamic functions has been optimized by using the CALPHAD technique. The calculations based on the obtained descriptions show good agreement with experimental phase diagrams and thermodynamic values.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Materials Science (General)
Authors
Yu Wang, Yimin Sun, Zhiyu Qiao, Xinyu Ye, Zhisen Ma, Xiangzhen Meng,