Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10676995 | Applied Clay Science | 2005 | 7 Pages |
Abstract
Two commercial acid-activated montmorillonites (F24 and F124) were exchanged with different cations (Al3+, Cr3+, Fe3+, and Ni2+). The catalytic activity of the acid- and the ion-exchanged clays was measured using the isomerization of cis- and trans-2-butene at 300 °C to yield the corresponding isomers. The order of activity for the acid- and the different cation-exchanged forms was: acid clays >Al3+âNi2+>Cr3+>Fe3+, which slightly correlated with the acidity values determined by cyclohexylamine desorption and the d001 spacing obtained from integral series of reflections. The maximum conversion for the isomerization of cis-2-butene was â75% for F24 and F124, while the maximum conversion for the isomerization of trans-2-butene was â53% for F24 and F124. Cracking produced propylene and methane and their amounts increased with the acidity.
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Geochemistry and Petrology
Authors
Alexander Moronta, José Luengo, Yorge RamÃrez, Jackeline Quiñónez, Eduardo González, Jorge Sánchez,