Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11000512 | Electrochimica Acta | 2018 | 24 Pages |
Abstract
Composite Co-based electrocatalysts exhibit synergetic electrochemical performance and play important role in water-splitting devices. Previous MOF-template route to targeting Co-electrocatalysts relies mainly on regular Co-MOFs particles, and how to obtain hybrid Co-electrocatalysts with adjustable compositions is still challenging. Here we present a facile route to obtain hybrid Co-electrocatalysts with tunable compositions by impregnating different amount of Co2+ ions in common Fe-MOF particles followed by a calcination process. Four different Co-based electrocatalysts with regular porous structures have been developed and their OER activities are investigated. Among them, metallic Co-containing composite electrocatalysts (Co/CoO/CoFe2O4) exhibit both HER and OER activity, and they are applicable to overall water splitting. This work shares a new strategy to achieve porous Co-based composite electrocatalysts and a simple route to tailor their compositions and activities.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Jingyun Wang, Cao Cui, Rongbin Lin, Chunhui Xu, Jin Wang, Zhengquan Li,