Article ID Journal Published Year Pages File Type
11000512 Electrochimica Acta 2018 24 Pages PDF
Abstract
Composite Co-based electrocatalysts exhibit synergetic electrochemical performance and play important role in water-splitting devices. Previous MOF-template route to targeting Co-electrocatalysts relies mainly on regular Co-MOFs particles, and how to obtain hybrid Co-electrocatalysts with adjustable compositions is still challenging. Here we present a facile route to obtain hybrid Co-electrocatalysts with tunable compositions by impregnating different amount of Co2+ ions in common Fe-MOF particles followed by a calcination process. Four different Co-based electrocatalysts with regular porous structures have been developed and their OER activities are investigated. Among them, metallic Co-containing composite electrocatalysts (Co/CoO/CoFe2O4) exhibit both HER and OER activity, and they are applicable to overall water splitting. This work shares a new strategy to achieve porous Co-based composite electrocatalysts and a simple route to tailor their compositions and activities.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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