Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11000678 | The Journal of Chemical Thermodynamics | 2019 | 34 Pages |
Abstract
In this work, we reported the new experimental data of densities, speeds of sound, and refractive indices for four binary mixtures: {2-phenoxyethanol (2PhEE)â¯+â¯1-propanol or 2-propanol or 1-butanol or 2-butanol) over the entire composition range and at temperatures of (293.15, 303.15, 313.15 and 323.15)â¯K and at pressure pâ¯=â¯0.1â¯MPa. From these experimental data, thermodynamics properties: excess molar volume, isentropic compressibility, deviation in isentropic compressibility and deviation in refractive indices were calculated. Excess molar volume, deviation in isentropic compressibility and deviation in refractive indices data have been correlated using the Redlich-Kister equation. From the obtained results, a discussion was carried out in terms of nature of intermolecular interactions and structure factors in these binary mixtures.
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Chemical Engineering
Chemical Engineering (General)
Authors
Hamdi Makhlouf, Natalia Muñoz-Rujas, Fernando Aguilar, Boucif Belhachemi, Eduardo A. Montero, Indra Bahadur, Latifa Negadi,