Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11000683 | The Journal of Chemical Thermodynamics | 2019 | 11 Pages |
Abstract
Fluorosilicate glass optical fibres are interesting hosts for rare-earth ions. When doped with ytterbium, for example, such fibres exhibit unique and beneficial fluoride-like spectroscopic features despite the host being predominantly silica. This work investigates the thermo-physical and chemical properties of Yb-doped fluorosilicate optical fibres in order to gain insight into the local structure about the rare earth and better understand the origins of their spectroscopic properties. Experimental findings, which suggest that the rare earth is embedded in a fluorine-rich environment in the fluorosilicate glass, are corroborated using molecular dynamic simulations.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Maxime Cavillon, Benoit Faugas, Junjie Zhao, Courtney Kucera, Baris Kukuoz, Peter Dragic, Xvsheng Qiao, Jincheng Du, John Ballato,