| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 11001601 | Journal of Organometallic Chemistry | 2018 | 24 Pages |
Abstract
The nitrosyl complex [CpMo(CO)2(NO)] (Cpâ¯=â¯Î·-C5H5) reacts with the nickel dithiolene complex [Ni(S2C2Ph2)2] to give the expected dimolybdenum complex [Mo2(NO)2(μ-S2C2Ph2)2Cp2], but the major product consists of two separable isomers of the tetranuclear complex [Mo2Ni2(NO)2(μ-S2C2Ph2)4Cp2], which comprises two CpMo(NO)Ni(S2C2Ph2)2 units joined through bridging sulfur atoms.129
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Dithiolene transfer to the molybdenum nitrosyl complex [CpMo(CO)2(NO)]: Formation of bimetallic complexes](/preview/png/11001601.png "First Page Preview: Dithiolene transfer to the molybdenum nitrosyl complex [CpMo(CO)2(NO)]: Formation of bimetallic complexes")
Authors
Harry Adams, Liam Grimes, Michael J. Morris, Craig C. Robertson,