Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11001719 | Physica B: Condensed Matter | 2019 | 16 Pages |
Abstract
The methods of EPR and NEXAFS spectroscopy were employed for the study of BiNb1-xFexO4-δ solid solutions of triclinic and orthorhombic modifications. The analysis of the NEXAFS Fe2p-spectra of iron oxides and the iron-containing solid solutions revealed that Fe atoms were mainly in an oxidation state of +3. In the EPR spectra of the BiNb1-xFexO4-δ samples of orthorhombic modification, a broad line with the center at g of 2.16-2.37 was registered along with the low-intensity signal with a g-factor of â¼4.3 observed on its low-field wing. EPR spectra of the triclinic structure samples exhibited a complex system of lines in the range of 80-300â¯mT. An intense complex line having features at g of 4.74-4.80, 4.04-4.10 and 3.76-3.80 was recognized in the low-field signal. The low-field wing of the line was complicated by a shoulder with g of 5.3 and by a line in the form of an absorption signal with g of 7.7-8.0. As a result of the modeling of EPR spectra, the spin-Hamiltonian parameters of Fe(III) in the structure of BiNb1-xFexO4-δ of triclinic modification were obtained.
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
N.Ð. Zhuk, V.P. Lutoev, V.A. Belyy, B.Ð. Makeev, D.S. Beznosikov, S.V. Nekipelov, M.V. Yermolina,