Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11003336 | Separation and Purification Technology | 2019 | 17 Pages |
Abstract
The disadvantage of the traditional ammonium tetramolybdate (ATM) production process is a large consumption of nitric acid. Therefore a novel process for the generation of ammonium isopolymolybdate solution from ammonium molybdate solution using bipolar membrane electrodialysis (BMED) was developed and the batch experiment was carried out in this paper. The BMED process was studied to optimize various parameters such as initial base solution, final electrolytic pH value of salt solution, current density, initial NH4HCO3 concentration of base solution and Mo concentration in feed solution. The average current efficiency was 82%, the power consumption was 0.058â¯kWh/mol NH4+ or 0.887â¯kWh/mol Mo, and the recovery rate of Mo reached 99.4% under the optimal conditions of a current density of 500â¯A/m2, an initial Mo concentration of 173â¯g/L in the salt compartment, an initial NH4HCO3 concentration 2.0â¯mol/L in the base compartment, an initial (NH4)2CO3 concentration of 1.0â¯mol/L in the electrode solution and 32â¯Â±â¯0.5â¯Â°C and a final solution pH of 4.0 in the salt compartment.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Guiqing Zhang, Qiang Wang, Wenjuan Guan, Li Zeng, Qinggang Li, Zuoying Cao, Liansheng Xiao, Qin Zhou,