Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11005948 | Solid State Ionics | 2018 | 6 Pages |
Abstract
Layered Li2MnO3 mixed with sucrose is heat-treated at low temperature under air atmosphere. A uniform carbon layer is found to be coated on Li2MnO3 active material according to the analysis of scanning electron microscopy and transmission electron microscopy. The thin carbon coating is in favor of good electrical contact between the cathode active particles as well as prevents the direct contact between the active material and electrolyte. Based on X-ray diffraction and X-ray photoelectron spectroscopy analyses, the crystal structure of Li2MnO3 is not degraded and some Mn4+ on the surface is reduced to Mn3+ during the carbon coating process in air. The galvanostatic charge-discharge results show the carbon coated Li2MnO3 exhibits greatly improved discharge capacity and rate capability. The carbon modified Li2MnO3 treated for 40â¯min delivers initial discharge capacity of 280.5â¯mAhâ¯gâ1 at 10â¯mAâ¯gâ1 and 117.5â¯mAhâ¯gâ1 at 400â¯mAâ¯gâ1 while the pristine sample only delivers 229.1 and 51.8â¯mAhâ¯gâ1 at the same current densities. The significantly improved high rate performance demonstrates this synthesis route is a reliable approach for conductive carbon coating on cathode materials used in lithium ion batteries.
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Lilong Xiong, Mengting Sun, Youlong Xu, Xianfeng Du, Xiang Xiao,