Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11024393 | Dyes and Pigments | 2019 | 19 Pages |
Abstract
A ladder-type Ï-system PDIPY that bearing perylene diimide and pyrene units have been developed for constructing non-fullerene acceptors. The vinyl bridged PDIPY dimer PDIPY-V and polymer PPDIPY-V have been synthesized via bromonation and Stille coupling recation. PDIPY-V and PPDIPY-V exhibit intense and broad absorption within 400-650â¯nm that complement the absorption spectra of the narrow bandgap polymeric donors. DFT calculation indicated that PDIPY-V and PPDIPY-V hold highly twisted structure, which prevent the formation of ÏâÏ stacking and crystallization in the aggregated states. The grazing-incidence wide-angle X-ray scattering (GIWAXS) and atomic force microscopy (AFM) investigations confirmed the amorphous nature of the pure films and the PDIPY-V/PPDIPY-V:PTB7-Th blend films. The PDIPY-V:PTB7-Th based photovoltaic device showed a poor performance due to the small LUMO offset of donor and acceptor. While the PPDIPY-V:PTB7-Th based device showed a high PCE of 5.20%, indicating the PDIPY derivatives are promising non-fullerene acceptors for polymer solar cells.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Jiarun Cheng, Bing Li, Xiaojie Ren, Feng Liu, Hongchi Zhao, Haijun Wang, Yonggang Wu, Weiping Chen, Xinwu Ba,