Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
11028278 | Electrochimica Acta | 2018 | 49 Pages |
Abstract
We report here a facile, template-free and one-step solvothermal approach for the synthesis of high-temperature stable gold/titania nanocomposite (NCs), providing a new, simple, quick and inexpensive wet-chemical route. Our approach is based on the assembly of gold salt and titanium butoxide in dimethyl sulfoxide (DMSO). Also, we present here, for the first time, a cathodically activated Au/TiO2 catalyst with Pt/C activity for the hydrogen evolution reaction (HER) in 0.5â¯Mâ¯H2SO4 in the dark. The as-prepared (unactivated) Au/TiO2 NCs exhibits considerable electrocatalytic activity for H2 generation in the dark, with a low onset potential (EHER) of â64â¯mV vs. RHE, a Tafel slope (-bc) of 60â¯mV decâ1 and an exchange current density (jo) of 0.12â¯mAâ¯cmâ2. Long-term stability and durability tests in 0.5â¯Mâ¯H2SO4, employing cyclic voltammetry technique (10,000 of repetitive cycling) and 72â¯h of chronoamperometry measurements at a high cathodic potential (cathodic activation), reveal that the electrocatalyst activates during such aging processes yielding an activated Au/TiO2 catalyst with Pt/C-like activity for H2 generation (EHER -3â¯mV, -bc: 35â¯mV decâ1, and jo: 0.95â¯mAâ¯cmâ2). The outstanding HER activity of the activated catalyst is discussed.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Amine Mezni, Mohamed M. Ibrahim, Maged El-Kemary, Abdallah A. Shaltout, Nasser Y. Mostafa, Jacek Ryl, T. Kumeria, Tariq Altalhi, Mohammed A. Amin,