Article ID Journal Published Year Pages File Type
11029610 Journal of Organometallic Chemistry 2018 25 Pages PDF
Abstract
The title compounds are accessed by the reaction of Grubbs' first generation catalyst and platinum(II) dichloride complexes with trans dialkyl selenide ligands Se((CH2)6CH = CH2)2, and subsequent substitution of the chloride ligands. They are isolated as mixtures of easily interconverted syn/anti isomers with respect to the selenium lone pairs; the latter orientation is found in crystal structures. Attempted hydrogenations release the novel diselanamacrocycle Se(C14H28)2Se.218
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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