Article ID Journal Published Year Pages File Type
1180941 Chemometrics and Intelligent Laboratory Systems 2012 5 Pages PDF
Abstract
► The generalised case of sequential standard addition calibration has been described. ► An expression for the gradient, systematic bias and relative precision associated with the technique has been derived. ► It has been shown that for single point addition the generalised case is equivalent to previous, non-generalised, considerations. ► The linearity of multi-point addition shows a strong dependence on the solution mass and analyte concentration. ► The findings provide a new tool for analytical chemists to quantify analyte content in unknown solutions.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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