Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1180941 | Chemometrics and Intelligent Laboratory Systems | 2012 | 5 Pages |
Abstract
⺠The generalised case of sequential standard addition calibration has been described. ⺠An expression for the gradient, systematic bias and relative precision associated with the technique has been derived. ⺠It has been shown that for single point addition the generalised case is equivalent to previous, non-generalised, considerations. ⺠The linearity of multi-point addition shows a strong dependence on the solution mass and analyte concentration. ⺠The findings provide a new tool for analytical chemists to quantify analyte content in unknown solutions.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Richard J.C. Brown, Thomas P.S. Gillam,