Article ID Journal Published Year Pages File Type
1180963 Chemometrics and Intelligent Laboratory Systems 2013 7 Pages PDF
Abstract

The Candecomp/Parafac (CP) model decomposes a three-way array through components. In the practical use of CP, degeneracy may arise, i.e. CP parameter matrices with diverging, highly collinear and uninterpretable components. A frequently applied remedy to degeneracy is to fit a CP model with orthogonality constraints on one of the component matrices. However, this does not guarantee that the so-extracted components well resemble the true ones because the occurrence of degeneracy does not imply the orthogonality of the true components. For this reason, a new CP method involving a particular ridge regularization term (hence, called CP-Ridge) is introduced. It solves the degeneracy problem admitting an overall maximum level of collinearity among the components. A simulation experiment is performed in order to illustrate the properties of CP-Ridge and to compare its performance with those of some other competitors available in the literature.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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