Automatic determination of nickel in foods by flame atomic absorption spectrometry

A new sensitive and low cost flow injection method that combines acid extraction, preconcentration and flame atomic absorption spectrometric determination of nickel in food samples at μg/g levels is described. The dynamic acid extraction step was carried out by using a continuous ultrasound-assisted extraction system. The acid extract was preconcentrated on-line on a minicolumn packed with a chelating resin (Serdolit Che, with iminodiacetic groups) and nickel was eluted with diluted hydrochloric acid, being continuously monitored by flame atomic absorption spectrometry. An experimental design (Plackett-Burman 26 × 3/16) is used to optimise the methodology proposed. The method allowed a total sampling frequency of 13–28 samples per hour. Good precision of the whole procedure (1.9–3.6% expressed as relative standard deviation) and a detection limit of 0.12 μg/g, for 60 mg of sample were achieved. The method was successfully applied to the determination of trace amounts of nickel in food samples.