Article ID Journal Published Year Pages File Type
1192214 International Journal of Mass Spectrometry 2012 11 Pages PDF
Abstract
► b2 oxazolone formation requires a b3 anhydride intermediate in protonated VGEIG. ► The b3 VGEIG anhydride is an intermediate to formation of b3 macrocyclic structures. ► Data suggest that the b3 macrocycle is an 11-membered ring structure. ► Alpha proton scrambling is demonstrated in VXEIG analogs and a new pathway proposed.
Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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