| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1192889 | International Journal of Mass Spectrometry | 2011 | 9 Pages |
Abstract
⺠CCl3+ reacts with acetophenone in the gas-phase through three different channels. ⺠One of the main reaction products, C9H7Cl2O+, presents an interesting structural problem. ⺠IRMPD of C9H7Cl2O+ ions proceeds by loss of either Cl or CH3 in violation of the even-electron rule. ⺠Theoretical calculations and reactivity studies clearly show the formation of two isomeric C9H7Cl2O+ ions.
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Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Tatiana Giroldo, Camila Bacellar Cases da Silveira, José M. Riveros,