| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1193409 | International Journal of Mass Spectrometry | 2011 | 4 Pages |
Abstract
ⶠFluorinated aluminate anions (AlHmF4âmâ) can be formed in the gas phase by ionization of diethylmethylamine-alane with molecular fluorine. ⶠEnergy-resolved collision-induced dissociation is used to measure fluoride affinities of the alanes. ⶠThe measured fluoride affinities agree with predictions obtained from coupled-cluster calculations with very large basis sets. ⶠFluoride affinities reflect the extent of positive charge character on the aluminum in the alanes.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Jamelle K.P. Williams, Paul G. Wenthold,