Article ID Journal Published Year Pages File Type
1193852 International Journal of Mass Spectrometry 2008 13 Pages PDF
Abstract

An ideal “Elliptical Penning Trap” is an ideal cylindrically symmetric Penning trap with an additional electrostatic quadrupolar potential ∝κ(x2−y2)∝κ(x2−y2). This configuration is here investigated for arbitrary strength κκ of the additional potential. Aside from the decoupled axial motion the system is characterized by a generalized cyclotron and a generalized magnetron frequency. While the former depends only weakly on κκ, the magnetron frequency decreases rapidly with increasing κκ, vanishing at a maximum value κmax⁡κmax⁡ which represents the stability limit for the magnetron motion. Magnetron orbits are elliptical, with their numerical excentricity tending toward unity as κκ approaches its maximum value. A complete and rigorous description of the dynamics of the ideal elliptical trap is given, its approximate physical realization by use of a segmented ring electrode is discussed, and the frequency shifts expected for a real elliptical trap on account of anharmonic potential terms and of image charges are estimated by means of classical canonical perturbation theory. The accompanying paper by Breitenfeldt et al. [M. Breitenfeldt, S. Baruah, K. Blaum, A. Herlert, M. Kretzschmar, F. Martinez, G. Marx, L. Schweikhard, N. Walsh, Int. J. Mass Spectrom. (2008) this issue] reports corresponding experimental investigations.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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