Metal dicarbides as intermediate species in thermal ion formation mechanisms

Lanthanide elements (lanthanum to lutetium) and actinide elements (uranium and plutonium) adsorbed onto resin beads and mounted on rhenium filaments were studied as thermal ionization sources. Temperatures at which these ion sources gave maximum intensities were measured for each of these elements. The temperature trends correlate with the dissociation energies of the corresponding metal dicarbide compounds. The metal dicarbide functions as a carrier to take the lanthanide and actinide elements to higher temperatures than would be attainable otherwise. This results in release of the atomic species at a higher temperature where ionization probability is significantly increased.

Graphical abstractA systematical study of the ion emission temperature from thermal ion sources containing lanthanide elements using thermal ionization mass spectrometry.Figure optionsDownload full-size imageDownload as PowerPoint slide