| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1194245 | International Journal of Mass Spectrometry | 2012 | 9 Pages |
Abstract
⺠Abundance mass spectra of M+(H2O)n (M = Li, Na, K, Rb and Cs) have been recorded. ⺠Magic number peaks in abundance spectra and in evaporation spectra are identical. ⺠Reactions with D2O show that proton mobility is insignificant in all M+(H2O)n. ⺠Quantum chemical calculations show that activation energies for H/D exchange are high. ⺠These clusters will be useful for benchmarking in future studies of H/D exchange.
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Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Alexey Sergeevich Zatula, Mauritz Johan Ryding, Patrik Urban Andersson, Einar Uggerud,